Yep, that's Spider-Man.
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It was recently revealed that Spider-Man would be coming to Marvel's Avengers on November 30th. Just keep in mind that Spider-Man and his story content are exclusive to the PlayStation 4 and PlayStation 5 versions of Marvel's Avengers.

Today, IGN got an exclusive first look at Spider-Man's intro video into Marvel's Avengers.

The trailer is a cinematic that introduces the web slinger. We don't see any gameplay in the video but we do get an idea for Spidey's moveset. He looks like he'll be able to swing on webs and crawl on walls. You know, like a spider.

The cinematic shows Peter ambushing a group of A.I.M. soldiers that have taken hostages. Neither Square Enix nor Crystal Dynamics have said who is providing the voice for Spider-Man in this new content.